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Updated: Feb 21, 2026
Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
A cluster-based mesoporous Ti-MOF with sodalite supercages
Chao Wang1, Chao Liu, Xiang He
1State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, China. szm@ciac.ac.cn.
Abstract:
The cooperative assembly of a hexagonal column shaped [Ti6O6][iPrO]66+ cluster and rhomboid Cu2I2 dimers using isonicotinic acid results in an unprecedented three-dimensional (3D) highly crystalline cluster-based Ti-MOF that features both giant sodalite cages with an inner diameter of 2.8 × 3.2 nm2 and 3D open square channels.
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