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Updated: May 2, 2026

Scalable Nanohelices for Predictive Studies and Enhanced 3D Visualization
Published on: November 12, 2014
Chiral Nanographene Propeller Embedding Six Enantiomerically Stable [5]Helicene Units
Veronika Berezhnaia1, Myriam Roy1, Nicolas Vanthuyne2
1Aix Marseille Université , CNRS, CINAM, 13288 Marseille, France.
Abstract:
A one-step synthesis of a nanographene propeller with a D3-symmetry was obtained starting from 7,8-dibromo[5]helicene by Yamamoto nickel(0) couplings. It afforded a chiral polyaromatic hydrocarbon (PAH) embedding six enantiomerically stable [5]helicene units. This dense accumulation of helical strain resulted in a distorted geometry, but stable stereochemistry. The conformational, structural, chiroptical, and photophysical properties of the molecule are reported.
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