TiO₂-Based Nanomaterials for the Production of Hydrogen and the Development of Lithium-Ion Batteries

The photocatalytic activity of different titanium oxide nanowires containing gold (Au@TiO₂NWs), and gold-graphene (Au@TiO₂NWs-graphene), was evaluated by studying the reaction of hydrogen production by water splitting under UV-vis light. The composites showed high surface areas, with values above 300 m² per gram, even after the incorporation of gold and graphene on the surface of titanium oxide nanowires. The highest hydrogen production of Au@TiO₂NWs was 1436 μmol h^-1 g^-1, under irradiation at 400 nm, and with a gold loading of 10 wt %. This photocatalytic activity was 11.5 times greater than that shown by the unmodified TiO₂NWs. For the Au@TiO₂NWs-graphene composites, the highest hydrogen amount obtained was 1689 μmol h^-1 g^-1, at loadings of 10 and 1 wt % of gold and graphene, respectively. The photocatalytic activity of the gold-graphene compounds was 1.2 times greater than that shown by the titanium oxide catalysts and 13.5 times higher than the bare TiO₂NWs. Even at wavelengths greater than 500 nm, the compounds exhibited yields of hydrogen above 1000 μmol h^-1 g^-1, demonstrating the high catalytic activity of the compounds. In addition, TiO₂-based materials are of great interest for energy storage and conversion devices, in particular for rechargeable lithium ion batteries. TiO₂ has a significant advantage due to its low volume change (<4%) during the Li ion insertion/desertion process, short paths for fast lithium ion diffusion, and large exposed surface, offering more lithium insertion channels. However, the relatively low theoretical capacity and electrical conductivity of TiO₂ greatly hamper its practical application. In this work, free-standing electrodes composed by TiO₂NWs and carbon nanotubes, CNT@TiO₂NWs, were used as anode materials for Li-ion batteries. As a result, the electronic conductivity and mechanical properties of the composite were greatly improved and a good cycling performance was obtained in these batteries. This research shows the potential of TiO₂-based materials for the development of new catalysts for hydrogen production and energy storage systems.