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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
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Reduction of Alkenes: Catalytic Hydrogenation02:13

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Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Updated: Feb 20, 2026

Simple Methods for the Preparation of Non-noble Metal Bulk-electrodes for Electrocatalytic Applications
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Highly Efficient Dual Active Palladium Nanonetwork Electrocatalyst for Ethanol Oxidation and Hydrogen Evolution.

Halima Begum1, Mohammad Shamsuddin Ahmed1, Seungwon Jeon1

  • 1Department of Chemistry and Institute of Basic Science, Chonnam National University , Gwangju 500-757, Republic of Korea.

ACS Applied Materials & Interfaces
|October 26, 2017
PubMed
Summary

A tunable palladium nanonetwork (PdNN) efficiently catalyzes ethanol oxidation and hydrogen evolution reactions. This dual electrocatalyst offers superior performance and stability compared to platinum/carbon, advancing energy conversion applications.

Keywords:
dual active electrocatalystethanol oxidationhydrogen evolutionnanonetworkspalladium

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Nanotechnology

Background:

  • Developing efficient electrocatalysts is crucial for energy conversion technologies.
  • Palladium-based nanomaterials show promise for catalyzing key reactions.

Purpose of the Study:

  • To synthesize and characterize a tunable palladium nanonetwork (PdNN) for catalyzing ethanol oxidation reaction (EOR) and hydrogen evolution reaction (HER).
  • To evaluate the electrocatalytic performance and stability of PdNN in alkaline media.

Main Methods:

  • PdNN synthesis via a simple chemical route using zinc precursor and CTAB surfactant.
  • Electrochemical characterization using voltammetric methods in alkaline electrolyte.
  • Tuning network thickness by adjusting CTAB concentration.

Main Results:

  • PdNN exhibited a 2.2-fold higher electrochemical surface area than commercial Pt/C.
  • Achieved 2.6-fold higher mass activity for EOR with reduced CO2 production.
  • Demonstrated comparable overpotential for HER (110 mV @ 10 mA cm-2) to Pt/C with improved kinetics.
  • PdNN showed enhanced electrocatalytic activity and stability for both EOR and HER.

Conclusions:

  • Tunable PdNN is a highly efficient, dual electrocatalyst for EOR and HER.
  • The nanonetwork structure facilitates electron transport and increases active sites.
  • PdNN presents a superior alternative to Pt/C for energy conversion applications.