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Updated: Feb 20, 2026
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Published on: November 11, 2013
Nanoscale Manipulation of Spinel Lithium Nickel Manganese Oxide Surface by Multisite Ti Occupation as
Biwei Xiao1, Hanshuo Liu2, Jian Liu1
1Department of Mechanical and Materials Engineering, University of Western Ontario, London, ON, N6A 5B9, Canada.
Abstract:
A novel two-step surface modification method that includes atomic layer deposition (ALD) of TiO2 followed by post-annealing treatment on spinel LiNi0.5 Mn1.5 O4 (LNMO) cathode material is developed to optimize the performance. The performance improvement can be attributed to the formation of a TiMn2 O4 (TMO)-like spinel phase resulting from the reaction of TiO2 with the surface LNMO. The Ti incorporation into the tetrahedral sites helps to combat the impedance growth that stems from continuous irreversible structural transition. The TMO-like spinel phase also alleviates the electrolyte decomposition during electrochemical cycling. 25 ALD cycles of TiO2 growth are found to be the optimized parameter toward capacity, Coulombic efficiency, stability, and rate capability enhancement. A detailed understanding of this surface modification mechanism has been demonstrated. This work provides a new insight into the atomic-scale surface structural modification using ALD and post-treatment, which is of great importance for the future design of cathode materials.
