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Efficient Synthesis of Polyfunctionalized Benzenes in Water via Persulfate-promoted Benzannulation of α,β-Unsaturated Compounds and Alkynes
Published on: December 16, 2019
Photochemical synthesis of benzo[f]chromene
1Department of Chemistry, Faculty of Science, University of Jiroft, Jiroft, I.R. Iran. a.akbari@ujiroft.ac.ir.
Abstract:
The one-pot photocatalytic synthesis of benzo[f]chromene was performed at room temperature by the addition of benzyl alcohol, malononitrile and β-naphthol in contact with an illuminated nano-SnO2/TiO2 composite. This study illustrated the potential of photochemical synthesis of benzo[f]chromene. A simple procedure was proposed for the synthesis of a nano-SnO2/TiO2 composite using the sol-gel method by hydrolysis of tin(iv) chloride and titanium(iv) chloride at room temperature in the presence of polyethylene glycol 200, diethanolamine, and distilled water. Scanning electron microscopy (SEM), X-ray diffraction (XRD), and FT-IR were employed to characterize the proposed photocatalyst.
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