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Quantitative Analysis by Thermogravimetry-Mass Spectrum Analysis for Reactions with Evolved Gases
Published on: October 29, 2018
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Experimental evaluation of main emissions during coal processing waste combustion
Margarita A Dmitrienko1, Jean C Legros2, Pavel A Strizhak1
1National Research Tomsk Polytechnic University, Tomsk 634050, Russia.
Environmental Pollution (Barking, Essex : 1987)
|November 3, 2017
Summary
Combusting coal processing filter cakes in coal-water slurries (CWS) and coal-water slurries containing petrochemicals (CWSP) can be optimized. Lowering combustion temperatures to 750-850°C significantly reduces carbon monoxide (CO) and carbon dioxide (CO2) emissions.
Area of Science:
- Environmental Science
- Chemical Engineering
- Energy Technology
Background:
- Coal processing generates millions of tons of filter cake waste annually in Russia, China, and India.
- Filter cakes are the largest volume coal processing waste, with potential for use in coal-water slurries (CWS) and coal-water slurries containing petrochemicals (CWSP).
- Previous studies have explored CWSP combustion, but direct measurement of CO and CO2 emissions from filter cake combustion is novel.
Purpose of the Study:
- To quantify carbon monoxide (CO) and carbon dioxide (CO2) emissions from the combustion of coal processing filter cakes.
- To evaluate the impact of combustion temperature on hazardous emissions.
- To determine optimal combustion conditions for minimizing environmental impact.
Main Methods:
- Direct measurement of CO and CO2 concentrations in emissions from filter cake combustion at temperatures ranging from 500 to 1000°C.
- Experimental testing of filter cake-based CWSP combustion in operational boilers.
- Comparative analysis of emissions from CWS and CWSP versus conventional solid fuels.
Main Results:
- CO and CO2 concentrations remained relatively constant at high temperatures (>900°C).
- Lowering combustion temperatures to 750-850°C sustainably reduced CO and CO2 emissions by 1.2-1.7 times.
- CWS and CWSP combustion significantly reduced NOx and SOx emissions compared to coal powder, with CO and CO2 levels comparable.
Conclusions:
- Low-temperature combustion (750-850°C) is feasible and environmentally beneficial for coal processing wastes.
- Optimizing combustion temperature is crucial for reducing CO and CO2 emissions in CWS and CWSP technologies.
- Sustainable and environmentally friendly utilization of coal processing wastes in CWS and CWSP requires low-temperature combustion strategies.
Keywords:
Coal processing wastesCoal-water slurry containing petrochemicalsGreenhouse gasesHazardous emissionsMaximum concentrations
