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Updated: Feb 19, 2026

OaAEP1-Mediated Enzymatic Synthesis and Immobilization of Polymerized Protein for Single-Molecule Force Spectroscopy
Published on: February 5, 2020
Polymer Amplified Enantioselectivity in the Fluorescent Recognition of Prolinol
Yachen Wang1, Lingling Hu1, Feng Zhao1
1Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu, 610064, China.
Abstract:
A 1,1'-bi-2-naphthol (BINOL)-aldehyde-based polymer has been synthesized that exhibits enantioselective fluorescent enhancement toward prolinol. It is found that the polymer shows greatly amplified enantioselectivity over the parent small-molecule sensor under the same conditions. This is attributed to the photoinduced electron transfer processes between the BINOL units in the polymer chain as well as the different steric environment provided by the polymer.
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