Spin reorientation and disordered rare earth magnetism in Ho₂FeCoO₆

We report the experimental observation of spin reorientation in the double perovskite Ho₂FeCoO₆. The magnetic phase transitions in this compound are characterized and studied through magnetization and specific heat, and the magnetic structures are elucidated through neutron powder diffraction. Two magnetic phase transitions are observed in this compound-one at [Formula: see text] K, from paramagnetic to antiferromagnetic, and the other at [Formula: see text] K, from a phase with mixed magnetic structures to a single phase through a spin reorientation process. The magnetic structure in the temperature range 200-45 K is a mixed phase of the irreducible representations [Formula: see text] and [Formula: see text], both of which are antiferromagnetic. The phase with mixed magnetic structures that exists in Ho₂FeCoO₆ gives rise to a large thermal hysteresis in magnetization that extends from 200 K down to the spin reorientation temperature. At T _N2, the magnetic structure transforms to [Formula: see text]. Though long-range magnetic order is established in the transition metal lattice, it is seen that only short-range magnetic order prevails in the Ho³⁺ lattice. Our results should motivate further detailed studies on single crystals in order to explore the spin reorientation process, spin switching and the possibility of anisotropic magnetic interactions giving rise to electric polarization in Ho₂FeCoO₆.