Enhancement of Dye-Sensitized Solar Cells Efficiency Using Mixed-Phase TiO₂ Nanoparticles as Photoanode

Dye-sensitized solar cell (DSSC) is a potential candidate to replace conventional silicon-based solar cells because of high efficiency, cheap cost, and lower energy consumption in comparison with silicon chip manufacture. In this report, mixed-phase (anatase and rutile nanoparticles) TiO₂ photoanode was synthesized to investigate material characteristics, carriers transport, and photovoltaic performance for future DSSC application. Field-emission scanning electron microscope (SEM), X-ray diffraction (XRD), photoluminescence (PL), and UV-visible spectroscopy were used to characterize mixed TiO₂ particles. Subsequently, various mixed-phase TiO₂ anodes in DSSC devices were measured by electrical impedance spectra (EIS) and energy efficiency conversion. The overall energy conversion efficiency of DSSC chip was improved as a result of the increase of rutile phase of TiO₂ (14%) in anatase matrix. Synergistic effects including TiO₂ crystallization, reduction of defect density level in energy band, longer lifetime of photoexcited electrons, and lower resistance of electron pathway all contributed to high efficiency of light energy conversion.