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Updated: Feb 19, 2026

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
Published on: April 10, 2018
Surface Modification of a NiS2 Nanoarray with Ni(OH)2 toward Superior Water Reduction Electrocatalysis in Alkaline
Ling Zhang1, Ibrahim Saana Amiinu2, Xiang Ren1
1College of Chemistry, Sichuan University , Chengdu 610064, China.
Abstract:
Interface engineering has been demonstrated to be effective in promoting hydrogen evolution reaction (HER) in an alkaline solution. Herein, we report that the HER activity of a NiS2 nanoarray on a titanium mesh (NiS2/TM) in alkaline media is greatly boosted by the electrodeposition of Ni(OH)2 onto NiS2 [Ni(OH)2-NiS2/TM]. Ni(OH)2-NiS2/TM only needs an overpotential of 90 mV to deliver 10 mA cm-2 in 1.0 M KOH. Density functional theory calculations confirm that Ni(OH)2-NiS2 has a lower water dissociation free energy and a more optimal hydrogen adsorption free energy than NiS2.
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