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Updated: Feb 19, 2026

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
The interplay between spin densities and magnetic superexchange interactions: case studies of mono- and trinuclear
Azar Aliabadi1, Bernd Büchner1,2, Vladislav Kataev1
1Leibnitz Institute for Solid State and Materials Research, IFW Dresden, Helmholtzstrasse 20, D-01069 Dresden, Germany.
Abstract:
For future molecular spintronic applications the possibility to modify and tailor the magnetic properties of transition-metal complexes is very promising. One of such possibilities is given by the countless derivatization offered by carbon chemistry. They allow for altering chemical structures and, in doing so, to tune magnetic properties of molecular spin-carrying compounds. With emphasis on the interplay of the spin density distribution of mononuclear and magnetic superexchange couplings of trinuclear bis(oxamato)-type complexes we review on efforts on such magneto-structural correlations.
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