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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

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Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

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Non-noble metal-catalysed carbonylative transformations.

Yahui Li¹, Yuya Hu, Xiao-Feng Wu

¹Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059 Rostock, Germany. Xiao-Feng.Wu@catalysis.de.

Chemical Society Reviews

|November 9, 2017

Summary

This review highlights non-noble metal catalysts for greener carbonylation reactions. It summarizes achievements in manganese, iron, copper, cobalt, and nickel-catalyzed carbonylative transformations, offering sustainable alternatives.

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Area of Science:

Catalysis
Green Chemistry
Organic Synthesis

Background:

Transition metal catalysts are crucial for efficient and selective chemical reactions.
Carbonylation reactions are vital for synthesizing carbonyl-containing compounds.
Existing literature predominantly focuses on noble metal catalysts for carbonylation.

Purpose of the Study:

To review and discuss the advancements in non-noble metal-catalyzed carbonylative transformations.
To highlight the potential of earth-abundant metals in catalysis.
To provide a comprehensive overview of manganese, iron, copper, cobalt, and nickel in carbonylation.

Main Methods:

Literature review of recent research on non-noble metal catalysis.
Analysis of reported carbonylative transformations using Mn, Fe, Cu, Co, and Ni catalysts.
Discussion of reaction mechanisms, efficiency, and selectivity.

Main Results:

Significant progress has been made in utilizing non-noble metals for carbonylation.
These catalysts offer sustainable and cost-effective alternatives to noble metals.
Various carbonylative transformations have been successfully achieved using earth-abundant metals.

Conclusions:

Non-noble metal catalysts are highly effective for carbonylative transformations.
These findings support the development of greener and more sustainable chemical processes.
Further research into non-noble metal catalysis holds great promise for the future of chemistry.