MWCNT/TiO₂ hybrid nano filler toward high-performance epoxy composite

In this work, multi-walled carbon nanotubes (MWCNTs) are decorated by TiO₂ nanoparticles and formed a new hybrid structure of filler (MWCNT/TiO₂ hybrid filler). The MWCNT/TiO₂ hybrid filler is reinforced in epoxy matrix and studied the mechanical and anti-corrosion properties of epoxy. The morphology of newly formed MWCNT/TiO₂ hybrid nano filler has been studied using transmission electron microscopy (TEM). Field Emission Scanning Electron Microscope (FESEM) images of tensile fracture surface confirmed the superior dispersion of MWCNT/TiO₂ in the epoxy matrix. The resultant MWCNT/TiO₂ hybrid-epoxy nanocomposite exhibits superior anti-corrosion and mechanical performance than the nanocomposite produced by loading of only MWCNTs or TiO₂ nanoparticles as well as neat epoxy. For example, tensile strength and storage modulus of epoxy increased by 61% and 43% respectively on loading of MWCNT/TiO₂ hybrid nano filler. Furthermore, the coating of MWCNT/TiO₂ hybrid-epoxy nanocomposite on mild steel reduces the corrosion rate upto 0.87×10^-3MPY from 16.81MPY.