Zn/V₂O₅ Aqueous Hybrid-Ion Battery with High Voltage Platform and Long Cycle Life

Aqueous zinc-ion batteries attract increasing attention due to their low cost, high safety, and potential application in stationary energy storage. However, the simultaneous realization of high cycling stability and high energy density remains a major challenge. To tackle the above-mentioned challenge, we develop a novel Zn/V₂O₅ rechargeable aqueous hybrid-ion battery system by using porous V₂O₅ as the cathode and metallic zinc as the anode. The V₂O₅ cathode delivers a high discharge capacity of 238 mAh g^-1 at 50 mA g^-1. 80% of the initial discharge capacity can be retained after 2000 cycles at a high current density of 2000 mA g^-1. Meanwhile, the application of a "water-in-salt" electrolyte results in the increase of discharge platform from 0.6 to 1.0 V. This work provides an effective strategy to simultaneously enhance the energy density and cycling stability of aqueous zinc ion-based batteries.