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Dissecting the Re-Os molybdenite geochronometer.

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Rhenium (Re) and osmium (Os) isotopes in molybdenite (MoS2) are heterogeneously distributed, challenging precise age dating. These elements are bound within or near molybdenite, complicating geochronological interpretations.

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Area of Science:

  • Geochemistry
  • Isotope Geology
  • Economic Geology

Background:

  • Molybdenite (MoS2) is a key mineral for rhenium (Re) and osmium (Os) isotope geochronology, crucial for dating ore deposits.
  • Accurate Re-Os dating relies on understanding the distribution of parent 187Re and daughter 187Os isotopes within molybdenite.
  • Previous assumptions about Re-Os isotope decoupling in molybdenite may hinder accurate mineralization age interpretations.

Purpose of the Study:

  • To investigate the distribution and controls on Rhenium (Re) and Osmium (Os) isotopes within molybdenite (MoS2).
  • To resolve discrepancies in Re-Os geochronology by examining element distribution at the micro and nano-scale.
  • To assess the impact of heterogeneous Re-Os distribution on the reliability of molybdenite dating methods.

Main Methods:

  • Chemical and isotope mapping of molybdenite (MoS2) grains using electron microprobe analysis (EMPA).
  • Nano-scale secondary ion mass spectrometry (NanoSIMS) for high-resolution isotopic and elemental imaging.
  • Analysis of molybdenite samples from representative porphyry copper-molybdenum deposits.

Main Results:

  • Demonstrated a heterogeneous distribution of Re (185,187Re) and Os (192Os) isotopes within molybdenite (MoS2) grains.
  • Showed that 187Re and 187Os isotopes are not decoupled as previously assumed, indicating a complex incorporation history.
  • Identified Re and Os as structurally bound or present as nanoparticles within or adjacent to molybdenite.

Conclusions:

  • The heterogeneous distribution and binding of Re and Os complicate microbeam dating of molybdenite (MoS2).
  • The observed 'nugget effect' of isotopes challenges the direct application of traditional Re-Os dating techniques.
  • Future geochronological studies must account for isotopic heterogeneity and element partitioning in molybdenite.