Self-sorted pore-formation in the construction of heteropore covalent organic frameworks based on orthogonal
Rong-Ran Liang1, Shun-Qi Xu, Zhong-Fu Pang
1CAS Key Laboratory of Synthetic and Self-assembly Chemistry for Organic Functional Molecules, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. China. xzhao@sioc.ac.cn.
Abstract:
Two heteropore COFs have been constructed by taking advantage of orthogonal dynamic covalent bonds. And an unprecedented self-sorted pore-formation in the polymerization process was observed, from which micropores with distinctive bonding manners were produced.
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