Diblock Copolymer PF-b-PDMAEMA as Effective Cathode Interfacial Material in Polymer Solar Cells

An alcohol-soluble diblock copolymer poly[2,7-(9,9-dihexylfluorene)]₁₅-block-poly[2-(dimethylamino)ethyl methacrylate]₇₅ (denoted as PF₁₅-b-PDMAEMA₇₅) was employed as the cathode interfacial layer (CIL) in p-i-n polymer solar cells (PSCs). PF₁₅-b-PDMAEMA₇₅ contains a conjugated rigid block and a nonconjugated flexible block grafted with polar amino groups, and it can effectively lower the work function of the Al cathode and decrease the series resistance of the devices. When applied as the CIL in PSCs based on poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexy)carbonyl]thieno[3,4-b]thiophenediyl]]:[6,6]-phenyl C71 butyric acid methyl ester, the champion power conversion efficiency of 8.80% was achieved, which is slightly higher than that of the PSCs using the well-known poly[(9,9-bis(3'-(N,N-dimethylamino)propyl)-2,7-fluorene)-alt-2,7-(9,9-dioctylfluorene)] as CIL under our experimental conditions, and much better than that of PSCs using Ca as CIL. The improvement of the performance is mainly attributed to the enhanced open-circuit voltage and fill factor. To the best of our knowledge, this is the first time a diblock copolymer has been used as a CIL in PSCs, and this study may provide a novel avenue for the design and synthesis of interfacial materials for high-performance PSCs.