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Published on: August 18, 2012
O2 activation at a trispyrazolylborato nickel(ii) malonato complex
S Hoof1, M Sallmann1, C Herwig1
1Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, 12489 Berlin, Germany. christian.limberg@chemie.hu-berlin.de.
Abstract:
To support mechanistic inferences made for an iron-based dioxygenase model, a nickel analogue, i.e. a TpNi-malonate (1) was prepared. 1 proved to represent a rare case of a nickel complex reacting with O2 in a controlled manner - mechanistically different from the iron case - and leads to hydroxylation of the malonate.
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