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Construction of luminescent high-nuclearity Zn-Ln rectangular nanoclusters with flexible long-chain Schiff base
Shiqing Wang1, Xiaoping Yang, Ting Zhu
1College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China.
Dalton Transactions (Cambridge, England : 2003)
|November 30, 2017
Abstract:
Three Zn-Ln clusters [Ln8Zn6(L1)2(OAc)20(O)2(NO3)4(OH)4] (Ln = Sm (1) and Nd (2)) and [Nd4Zn4(L2)2(OAc)10(NO3)2(OH)4] (3) were prepared using two long-chain Schiff base ligands. The Zn-Ln clusters exhibit interesting nano-square-like structures. Their visible and NIR luminescence properties were investigated.

