Multifunctional Moth-Eye TiO₂/PDMS Pads with High Transmittance and UV Filtering

This work reports a facile fabrication method for constructing multifunctional moth-eye TiO₂/polydimethylsiloxane (PDMS) pads using soft nano-imprinting lithography and a gas-phase-deposited thin sacrificial layer. Mesoporous TiO₂ nanoparticles act as an effective UV filter, completely blocking high-energy UVB light and partially blocking UVA light and forming a robust TiO₂/PDMS composite pad by allowing the PDMS solution to easily fill the porous TiO₂ network. The paraboloid-shaped moth-eye nanostructures provided high transparency in the visible spectrum and also have self-cleaning effects because of nanoroughness on the surface. Furthermore, we successfully achieved a desired multiscale-patterned surface by partially curing select regions using TiO₂/PDMS pads with partial UVA ray blockers. The ability to fabricate multifunctional polymeric pads is advantageous for satisfying increasing demands for flexible and wearable electronics, displays, and solar cells.