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Published on: June 14, 2019
Experimental study of dynamic contact angles on rough hydrophobic surfaces
Alireza Mohammad Karim1, Jonathan P Rothstein2, H Pirouz Kavehpour1
1Department of Mechanical and Aerospace Engineering, UCLA, Los Angeles, CA 90025, USA.
This study investigated the spreading of polyethylene glycol (PEG) solutions on rough Teflon surfaces. Surface roughness significantly impacts dynamic contact angles, with receding angles decreasing as capillary number increases.
Area of Science:
- Surface science
- Materials science
- Fluid dynamics
Background:
- Rough hydrophobic surfaces are crucial in various industrial applications.
- Understanding liquid behavior on these surfaces is essential for technological advancements.
- Polyethylene glycol (PEG) solutions are widely used and exhibit unique surface properties.
Purpose of the Study:
- To experimentally investigate the spreading dynamics of polyethylene glycol (PEG) solutions.
- To analyze the influence of surface roughness and PEG concentration on dynamic contact angles.
- To determine the relationship between capillary number and dynamic contact angles on rough hydrophobic surfaces.
Main Methods:
- Utilized the Wilhelmy plate method for precise contact angle measurements.
- Conducted experiments with varying concentrations of PEG solutions.
- Employed Teflon plates with controlled, differing degrees of surface roughness.
Main Results:
- Advancing dynamic contact angles showed weak dependence on the capillary number.
- Receding dynamic contact angles decreased with increasing capillary number.
- Surface roughness played a significant role in determining dynamic contact angles.
- Receding motion dynamics aligned with the molecular-kinetic theory.
- A power law relationship was established between receding dynamic contact angle and capillary number.
Conclusions:
- Surface roughness is a critical factor influencing liquid spreading dynamics on hydrophobic surfaces.
- The observed receding contact angle behavior supports theoretical models like the molecular-kinetic theory.
- Established a predictive power law for receding contact angles, valuable for surface design and applications.
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