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Updated: Feb 17, 2026

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Low-energy Cathodoluminescence for OxyNitride Phosphors
Published on: November 15, 2016
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A novel red-emitting K2Ca(PO4)F:Eu2+ phosphor with a large Stokes shift
H Daicho1, Y Shinomiya, K Enomoto
1Research & Development Department, Koito Manufacturing Co., 500, Kitawaki, Shimizu-ku, Shizuoka 424-8764, Japan. cl_ms@koito.co.jp.
Abstract:
We report a K2CaPO4F:Eu2+ phosphor with a new crystal structure. This phosphor has a large Stokes shift and converts near-ultraviolet light to red luminescence without absorption of other visible light. The mechanism was elucidated by applying a constrained density functional theory to the solved crystal structure.
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