Microporous Cobalt(II)-Organic Framework with Open O-Donor Sites for Effective C2H2 Storage and C2H2/CO2 Separation
Di-Ming Chen1, Xiao-Hui Liu1, Jia-Yue Tian1
1Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry , Zhengzhou 450002, P. R. China.
Abstract:
The self-assembly of a bifunctional organic ligand with a formate-bridged rod-shaped secondary building unit leads to a new microporous metal-organic framework (MOF). This MOF shows a moderately high C2H2 storage capacity (145 cm3/g) and an excellent adsorption selectivity for C2H2/CO2 (11) at room temperature. Furthermore, its discriminatory sorption behavior toward C2H2 and CO2 was probed by computational analysis in detail.
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