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Coordination-driven micellelization of block copolymers with gold(i) complexes induces remarkable phosphorescence
1Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, State Key Laboratory of Applied Organic Chemistry and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China. buwf@lzu.edu.cn.
Abstract:
The coordination-driven self-assembly of block copolymers with gold(i) complexes leads to the formation of spherical micelles with remarkable phosphorescence enhancements. The rising luminescence level increases unexpectedly with increasing the degree of polymerization of the noncoordinated block. Furthermore, one of the gold(i)-containing metallopolymers shows reversible mechanochromic luminescence.
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