Eco-friendly isolation of cellulose nanoplatelets through oxidation under mild conditions

Agave is recognized as a low recalcitrant material, which makes it a potential source to obtain nanocellulose. Aqueous dispersions (in water, H₂O₂, H₂O₂/H₂SO₄) of agave powder were heated at 120°C under vapor pressure (1kg/cm²). The resultant materials were observed with an optical microscope (OM), a laser scanning microscope (LSM) to obtain the thickness measurement and a scanning electron microscope (SEM) to observe morphology. Raman spectroscopy, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) were used to obtain the chemical structure. Cellulose nanoplatelets (CNPs) from Agave salmiana were successfully isolated under mild conditions. Physicochemical analysis indicates that lignin was removed in a single step oxidation with hydrogen peroxide in presence of sulfuric acid at low concentration (0.17M). The CNPs images revealed the presence of entangled cellulose nanofibrils (Ø≈14nm) along the nanoplatelets (thickness ≈80nm).