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Updated: Feb 16, 2026

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
Published on: December 16, 2022
A BN Aromatic Ring Strategy for Tunable Hydroxy Content in Polystyrene
Heidi L van de Wouw1, Jae Young Lee1, Elorm C Awuyah1
1Department of Chemistry, Johns Hopkins University, 3400 N. Charles St, Baltimore, MD 21218, USA.
Abstract:
BN 2-vinylnaphthalene, a BN aromatic vinyl monomer, is copolymerized with styrene under free radical conditions. Oxidation yields styrene-vinyl alcohol (SVA) statistical copolymers with tunable hydroxy group content. Comprehensive spectroscopic investigation provides proof of structure. Physical properties that vary systematically with hydroxy content include solubility and glass transition temperature. BN aromatic polymers represent a platform for the preparation of diverse functional polymeric architectures via the remarkable reaction chemistry of C-B bonds.
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