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Free Surface Relaxations of Star-Shaped Polymer Films
Emmanouil Glynos1, Kyle J Johnson2,3, Bradley Frieberg3,4
1Institute of Electronic Structure and Laser, Foundation for Research and Technology-Hellas, P.O. Box 1385, 711 10 Heraklion, Crete, Greece.
Abstract:
The surface relaxation dynamics of supported star-shaped polymer thin films are shown to be slower than the bulk, persisting up to temperatures at least 50 K above the bulk glass transition temperature T_{g}^{bulk}. This behavior, exhibited by star-shaped polystyrenes with functionality f=8 arms and molecular weights per arm M_{arm}
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