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Updated: Feb 16, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
(Ge2P2)2-: a binary analogue of P4 as a precursor to the ternary cluster anion [Cd3(Ge3P)3]3
Stefan Mitzinger1, Jascha Bandemehr, Kevin Reiter
1Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften, Philipps-Universität Marburg, Hans-Meerwein-Str. 4, 35043 Marburg, Germany. dehnen@chemie.uni-marburg.de.
Abstract:
The novel binary P4 analogue (Ge2P2)2- proved to be a suitable precursor for heteroatomic cluster synthesis. Over time in solution, it rearranges to form (Ge7P2)2-, as shown by NMR studies and X-ray diffraction. Reactions of (Ge2P2)2- with CdPh2 afford [K(crypt-222)]3[Cd3(Ge3P)3], containing an unprecedented ternary cluster anion with a triangular Cd3 moiety.
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