The reactivity of the Criegee intermediate CH₃CHOO with water probed by FTMW spectroscopy

The reaction of Criegee intermediates with water is one of the dominant removal mechanisms for these species in the atmosphere. The reactivity of alkyl substituted Criegee intermediates has been shown to be affected by the nature and location of the substituents. CH₃CHOO, acetaldehyde oxide, can be considered as a prototypical Criegee intermediate with a single alkyl substituent to examine the conformer specific reactivity for Criegee intermediates. Pulsed Fourier-transform microwave spectroscopy has been used to probe the products resulting from the reaction between CH₃CHOO and water. The hydrogen-bonded complex between CH₃CHOO and water together with the reaction product, hydroxyethyl hydroperoxide, were observed in the discharged plasma of a CH₃CHI₂/O₂/water gas mixture. The experimentally determined rotational parameters support the identification of the complex between water and the syn-CH₃CHOO conformer and two conformers of hydroxyethyl hydroperoxide, produced from the anti-CH₃CHOO conformer and water.