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Unraveling the Semiconducting/Metallic Discrepancy in Ni3(HITP)2

Michael E Foster1, Karl Sohlberg2, Mark D Allendorf1

  • 1Sandia National Laboratories , Livermore, California 94551-0969, United States.

The Journal of Physical Chemistry Letters
|January 11, 2018
PubMed
Summary

Defects in Ni3(HITP)2, a graphene-like material, create transport barriers by disrupting π-conjugation. These interface defects explain the observed semiconducting behavior, contradicting metallic predictions.

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