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Updated: Feb 15, 2026

Anionic Polymerization of an Amphiphilic Copolymer for Preparation of Block Copolymer Micelles Stabilized by π-π Stacking Interactions
Published on: October 10, 2016
Magic-Angle Stacking and Strong Intermolecular π-π Interaction in a Perylene Bisimide Crystal: An Approach for
Jiadong Zhou1, Wenqiang Zhang1, Xiao-Fang Jiang1
1Institute of Polymer Optoelectronic Materials and Devices, State Key Laboratory of Luminescent Materials and Devices, South China University of Technology , Guangzhou 510640, People's Republic of China.
Abstract:
A single crystal of N,N'-bis(4-methoxybenzyl)perylene-3,4,9,10-bis(dicarboximide) (mb-PBI) that possesses novel magic-angle stacking (M-type stacking) and strong intermolecular π-π interaction is achieved by physical vapor transport (PVT), which shows attractive optoelectronic functions such as efficient NIR emission and high electron mobility. In this special M-type staking, the strong Frenkel/CT mixing state promotes fluorescence and, importantly, the elimination of long-distance Förster resonance energy transfer enables the minimization of the possible fluorescence quenching, which ensure the highly efficient emission. Moreover, the strong π-π interaction elongates the "supramolecular conjugation" to reduce the energy gap and also benefits the electron mobility of the crystal. The experimental results clearly indicate that M-type staking is a novel approach to optimize the optoelectronic functions of organic semiconducting materials.
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