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Twisted Charge-Transfer Antennae for Ultra-Bright Terbium(III) and Dysprosium(III) Bioprobes
Anh Thy Bui1, Amandine Roux1, Alexei Grichine2
1Univ Lyon, ENS de Lyon, CNRS UMR 5182, Université Claude Bernard Lyon 1, Laboratoire de Chimie, 69342, Lyon, France.
Abstract:
The design of original twisted charge transfer antennae in which a non-planar geometry is enforced thanks to one or two bulky ortho-Me substituents allows us to prepare the corresponding ultra-bright TbIII and DyIII bioprobes. The brightness of the TbIII derivative compares well with that of the benchmark Tb-Lumi4 complex. The first bio-imaging experiments with a DyIII luminescent bioprobe are also reported.
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