Transient anomalous diffusion regimes in reversible adsorbing systems

A solvable, minimal model of diffusion in the presence of a reversible adsorption site is investigated. We show that the diffusive particles are influenced by the adsorbing site on transient times when they have anomalous subdiffusive behavior. However, the particle dispersion law crosses over to the normal diffusive regime on asymptotically long times. The subdiffusive regime is characterized by a t^{1/4} transient scaling with the same exponent as for the irreversible adsorption. On this transient time scale dominated by particle adsorption, there is a depletion of particles near the adsorbing site, and the typical width of the depletion zone grows in time as t^{1/4} with the same exponent as the subdiffusive dispersion. We show that having a nonzero desorption probability for the adsorbed particles produces a crossover towards normal diffusion on time scales larger than a characteristic reactive time, which we show scales with diffusivity and the adsorption site reactivity.