Manipulation of Nanoscale Intergranular Phases for High Proton Conduction and Decomposition Tolerance in BaCeO₃...

In many ion-conducting polycrystalline oxides, grain boundaries are generally accepted as rate-limiting obstacles to rapid ionic diffusion, often resulting in overall sluggish transport. Consequently, based on a precise understanding of the structural and compositional features at grain boundaries, systematic control of the polycrystalline microstructure is a key factor to achieve better ionic conduction performance. In this study, we clarify that a nanometer-thick amorphous phase at most grain boundaries in proton-conducting BaCeO₃ polycrystals is responsible for substantial retardation of proton migration and moreover is very reactive with water and carbon dioxide gas. By a combination of atomic-scale chemical analysis and physical imaging, we demonstrate that highly densified BaCeO₃ polycrystals free of a grain-boundary amorphous phase can be easily fabricated by a conventional ceramic process and show sufficiently high proton conductivity together with significantly improved chemical stability. These findings emphasize the value of direct identification of intergranular phases and subsequent manipulation of their distribution in ion-conducting oxide polycrystals.