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Updated: Feb 15, 2026

Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing
Published on: June 9, 2023
Could new U(ii) complexes be accessible via tuning hybrid heterocalix[4]arene? A theoretical study of redox and
Hong-Bo Zhao1, Ming Zheng, Georg Schreckenbach
1Key Laboratory of Functional Inorganic Material Chemistry of Education Ministry, School of Chemistry and Materials Science, Heilongjiang University, Harbin, 150080, China. panqjitc@163.com.
Abstract:
Tuning the building blocks of pyrrole and arene/pyridine in hybrid heterocalix[4]arene allows for the possible accessibility of several intriguing divalent uranium complexes, which are energetically stabilized by enhanced δ(U-Ar) bonds and further corroborated by computed UIII/II reduction potentials.
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