Related Experiment Video
Updated: Feb 15, 2026

IridiumIII Luminescent Probe for Detection of the Malarial Protein Biomarker Histidine Rich Protein-II
Published on: July 7, 2015
Solution, Solid-State, and Computational Analysis of Agostic Interactions in a Coherent Set of Low-Coordinate
Richard C Knighton1, Jack Emerson-King1, Jonathan P Rourke1
1Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry, CV4 7AL, UK.
Abstract:
A homologous family of low-coordinate complexes of the formulation trans-[M(2,2'-biphenyl)(PR3 )2 ][BArF4 ] (M=Rh, Ir; R=Ph, Cy, iPr, iBu) has been prepared and extensively structurally characterised. Enabled through a comprehensive set of solution phase (VT 1 H and 31 P NMR spectroscopy) and solid-state (single crystal X-ray diffraction) data, and analysis in silico (DFT-based NBO and QTAIM analysis), the structural features of the constituent agostic interactions have been systematically interrogated. The combined data substantiates the adoption of stronger agostic interactions for the IrIII compared to RhIII complexes and, with respect to the phosphine ligands, in the order PiBu3 >PCy3 >PiPr3 >PPh3 . In addition to these structure-property relationships, the effect of crystal packing on the agostic interactions was investigated in the tricyclohexylphosphine complexes. Compression of the associated cations, through inclusion of a more bulky solvent molecule (1,2-difluorobenzene vs. CH2 Cl2 ) in the lattice or collection of data at very low temperature (25 vs. 150 K), lead to small but statistically significant shortening of the M-H-C distances.
More Related Videos
13:07Optical Coherence Tomography Based Biomechanical Fluid-Structure Interaction Analysis of Coronary Atherosclerosis Progression
Published on: January 15, 2022
10:42Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
Published on: December 29, 2016
Related Concept Videos
Coordination Number and Geometry
Imaging Studies III: Computed Tomography
Coordination Compounds and Nomenclature
Electron Transport Chain: Complex III and IV
Area Computation by the Alternative Coordinate Method
Torts III
Quasi-intentional torts in healthcare involve acts where intent is not directed to harm an individual but results in harm due to careless or reckless speech.