Photomechanical motion of diarylethene molecular crystal nanowires

Crystalline nanowires composed of the photochromic diarylethene derivative 1,2-bis(2,4-dimethyl-5-phenyl-3-thienyl)perfluorocyclopentene (1a) are prepared and characterized. 200 nanometer diameter wires with a length of 60 microns are grown by slow solvent annealing in a porous anodic aluminum oxide template. The nanowires are oriented crystals, as determined by X-ray diffraction measurements, and can be liberated by dissolving the template in acid. They exhibit pronounced bending when exposed to ultraviolet light that can be reversed by visible light irradiation. The bending-unbending sequence can be repeated for more than 10 cycles without fatigue. This robustness results from the ability of the nanowires to maintain their crystallinity during the forward and reverse reactions. The small diameter of these nanowires allows them to achieve curvatures that are at least 40 times greater (200 mm^-1versus 5 mm^-1) than those observed for micron-thick diarylethene needles. This first demonstration of photomechanical nanostructures based on diarylethene photochromism opens up the possibility of making more complicated structures composed of this high-performance photochrome.