A velocity map imaging mass spectrometer for photofragments of fast ion beams

We present the details of a fast ion velocity map imaging mass spectrometer that is capable of imaging the photofragments of trap-cooled (≥7 K) ions produced in a versatile ion source. The new instrument has been used to study the predissociation of N₂O⁺ produced by electric discharge and the direct dissociation of Al₂⁺ formed by laser ablation. The instrument's resolution is currently limited by the diameter of the collimating iris to a value of Δv/v = 7.6%. Photofragment images of N₂O⁺ show that when the predissociative state is changed from ²Σ⁺(200) to ²Σ⁺(300) the dominant product channel shifts from a spin-forbidden ground state, N (⁴S) + NO⁺(v = 5), to a spin-allowed pathway, N^*(²D) + NO⁺. The first photofragment images of Al₂⁺ confirm the existence of a directly dissociative parallel transition (²Σ⁺_u ← ²Σ⁺_g) that yields products with a large amount of kinetic energy. D₀ of ground state Al₂⁺ (²Σ⁺_g) measured from these images is 138 ± 5 kJ/mol, which is consistent with the published literature.