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Double layer of platinum electrodes: Non-monotonic surface charging phenomena and negative double layer capacitance
Jun Huang1, Tao Zhou1, Jianbo Zhang2
1College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, People's Republic of China.
Abstract:
In this study, a refined double layer model of platinum electrodes accounting for chemisorbed oxygen species, oriented interfacial water molecules, and ion size effects in solution is presented. It results in a non-monotonic surface charging relation and a peculiar capacitance vs. potential curve with a maximum and possibly negative values in the potential regime of oxide-formation.
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