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On the Defect Structure of Biaxial Nematic Droplets
C Chiccoli1, L R Evangelista2, P Pasini1
1INFN Sezione di Bologna, Via Irnerio 46, 40126, Bologna, Italy.
Scientific Reports
|February 3, 2018
Summary
Increasing molecular biaxiality in nematic droplets expands the defect core size. This study reveals a non-universal behavior in confined liquid crystal systems, impacting molecular organization.
Area of Science:
- Condensed Matter Physics
- Materials Science
- Physical Chemistry
Background:
- Nematic droplets exhibit defects at their centers.
- Molecular biaxiality influences liquid crystal phase behavior.
- Surface anchoring conditions dictate molecular organization.
Purpose of the Study:
- To investigate the impact of molecular biaxiality on central defects in nematic droplets.
- To explore how increasing biaxiality affects molecular organization within confined systems.
- To compare lattice model results with continuum theory predictions.
Main Methods:
- Detailed Monte Carlo simulations using a lattice model.
- Employing a dispersive potential for biaxial mesogens.
- Comparison with continuum theory calculations.
Main Results:
- The defect core size increases with increasing molecular biaxiality.
- Both simulation and continuum theory approaches show this trend.
- A previously unreported non-universal behavior was observed.
Conclusions:
- Molecular biaxiality is a critical factor in determining defect characteristics in nematic droplets.
- The observed increase in defect core size suggests complex molecular ordering under confinement.
- Findings challenge existing universal assumptions about defect behavior in liquid crystals.
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