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Updated: Feb 15, 2026

Synthesis of pH Dependent Pyrazole, Imidazole, and Isoindolone Dipyrrinone Fluorophores using a Claisen-Schmidt Condensation Approach
Published on: June 10, 2021
Synthesis and Photophysical Properties of λ5-Phosphinines as a Tunable Fluorophore
Naoki Hashimoto1, Rika Umano1, Yusuke Ochi1
1Department of Materials Science and Biotechnology, Graduate School of Science and Engineering, Ehime University , 3 Bunkyo-cho, Matsuyama 790-8577, Japan.
Abstract:
A practical synthesis of a variety of λ5-phosphinines, which show distinct fluorescence both in solution and solid state, is described. Both C4-selective electrophilic substitutions and the following conversions realized an easy preparation of a wide range of derivatives having several substituents for electronic modification, which provides the potential for fine-tuning of the photophysical properties.
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