Ultrafiltration membrane fouling induced by humic acid with typical inorganic salts

Severe ultrafiltration (UF) membrane fouling is always induced by humic acid (HA). However, little attention has been paid to the influence of inorganic salts, and even the studies related have been limited to only a single kind of salt. In addition, the concentration of the inorganic salts reported in previous studies is much high. Herein, the effect of HA on UF membrane performance was investigated in the presence of typical inorganic salts, with concentrations similar to those in natural waters or actually used in most current water plants. The results showed that membrane performance was influenced little by monovalent inorganic salts (NaCl and KCl), while divalent inorganic salts (CaCl₂ and MgCl₂) could exacerbate the membrane fouling. For trivalent inorganic salts (AlCl₃·6H₂O and FeCl₃·6H₂O), floc adsorption was the dominant HA removing mechanism, and AlCl₃·6H₂O behaved better than FeCl₃·6H₂O. Relating to the floc properties, severe membrane fouling occurred with low dosage, while it was mitigated with high dosage. Compared with the trivalent inorganic salts, more severe membrane fouling was caused by divalent inorganic salts. Additionally, little synergistic or inhibitory effect occurred with mixtures of divalent inorganic salts and trivalent inorganic salts. Furthermore, analysis with the classical fouling models showed that cake filtration was the main fouling mechanism with/without inorganic salts. Based on the findings, we believe these different HA behaviors exhibited during coagulation process with inorganic salts will have a large potential application in UF membrane fouling alleviation in water treatment.