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Published on: April 11, 2020
Pectin microgel particles as high adsorption rate material for methylene blue: Performance, equilibrium, kinetic,
Li-Li Yu1, Li-Na Jiang2, Shu-Ya Wang1
1College of Chemical Engineering, Xinjiang Agricultural University, Urumchi 830052, Xinjiang, People's Republic of China.
Abstract:
The pectin gel has been proved to be an effective material for methylene blue (MB) removal, but it presented low adsorption rate. To get over the vice, the pectin microgel particles (PMP) was prepared. No matter high or low initial MB concentration, the PMP presented high adsorption rate with equilibrium time of 20min. The adsorption process based on monolayer adsorption and adsorbance of 284.09mg/g was obtained. What's more, the adsorption process was electrostatic adsorption with mean free energy of 74.223kJ/mol. The pseudo-second-order kinetic model fitted perfectly to the experimental data. The MB uptake was controlled by film diffusion mechanism. Furthermore, the recovery efficiency of regenerated PMP were higher than 80% after three cycles. The present study showed the PMP presented acceptable adsorbance, high adsorption rate and recovery efficiency. Thus, we believe that the PMP was a promising candidate for MB cleanup.
Insights
Pectin microgel particles (PMP) efficiently remove methylene blue (MB) with a high adsorption rate and capacity. This study highlights PMP as a promising material for effective MB cleanup from contaminated water sources.
Area of Science:
- Materials Science
- Environmental Chemistry
- Nanotechnology
Background:
- Pectin gel is effective for methylene blue (MB) removal but suffers from a low adsorption rate.
- Developing advanced materials is crucial for efficient water pollutant remediation.
Purpose of the Study:
- To prepare pectin microgel particles (PMP) to enhance MB adsorption rate and capacity.
- To investigate the adsorption mechanism, kinetics, and regeneration efficiency of PMP for MB removal.
Main Methods:
- Synthesis and characterization of pectin microgel particles (PMP).
- Batch adsorption experiments to determine MB adsorption kinetics and isotherms.
- Analysis using pseudo-second-order kinetic model and electrostatic adsorption principles.
- Regeneration and cycling tests to evaluate PMP reusability.
Main Results:
- PMP exhibited a high adsorption rate for MB, reaching equilibrium within 20 minutes.
- The maximum adsorption capacity of PMP was determined to be 284.09 mg/g, following monolayer adsorption.
- Adsorption followed pseudo-second-order kinetics, controlled by film diffusion, and was electrostatic in nature.
- Regenerated PMP maintained over 80% recovery efficiency after three cycles.
Conclusions:
- Pectin microgel particles (PMP) demonstrate superior performance in MB removal compared to pectin gel.
- PMP offers high adsorption capacity, rapid kinetics, and excellent reusability, making it a viable option for MB cleanup.
- The study validates PMP as a promising adsorbent for efficient removal of methylene blue from aqueous solutions.
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