Concentration of uranium in the soils of the west of Spain

While determining the uranium concentration in the rock (background level) and soils on the Iberian Massif of western Spain, several geochemical anomalies were observed. The uranium concentration was much higher than the geochemical levels at these locations, and several uranium minerals were detected. The proposed uranium background levels for natural soils in the west of Salamanca Province (Spain) are 29.8 mg kg^-1 in granitic rock and 71.2 mg kg^-1 in slate. However, the soil near the tailings of abandoned mines exhibited much higher concentrations, between 207.2 and 542.4 mg kg^-1. The calculation of different pollution indexes (Pollution Factor and Geo-accumulation Index), which reveal the conditions in the superficial horizons of the natural soils, indicated that a good percentage of the studied samples (16.7-56.5%) are moderately contaminated. The spatial distribution of the uranium content in natural soils was analysed by applying the inverse distance weighted method. The distribution of uranium through the horizons of the soils shows a tendency to accumulate in the horizons with the highest clay content. The leaching of uranium from the upper horizons and accumulation in the lower horizons of the soil could be considered a process for natural attenuation of the surface impacts of this radiogenic element in the environment. Environmental restoration is proposed in the areas close to the abandoned mining facilities of this region, given the high concentration of uranium. First, all the tailings and other mining waste would be covered with a layer of impermeable material to prevent leaching by runoff. Then, a layer of topsoil with organic amendments would be added, followed by revegetation with herbaceous plants to prevent surface erosion.