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Metal Corrosion and the Efficiency of Corrosion Inhibitors in Less Conductive Media
Published on: November 3, 2018
Biogenic corrosion inhibitor on mild steel protection in concentrated HCl medium
Muthukumar Krishnan1,2,3, Harinee Subramanian2, Hans-Uwe Dahms4,5,6
1Department of Marine Science, Bharathidasan University, Tiruchirappalli, 620 024, Tamil Nadu, India.
Abstract:
Turbinaria ornata (TO) extract was tested as green corrosion inhibitor on mild steel (MS) coupons in conc. HCl medium with an efficiency of 100% at 25 g l-1 during 5 min exposure. Antibacterial efficacy performed against 16 S rDNA identified marine biofilming bacteria (MBB) and human pathogenic bacteria (HPB). Maximum inhibition growth was 16 mm on MBB observed in Bacillus megaterium (MBF14 - AB894827) and 20 mm on HPB in Escherichia coli (B5 - NCIM 2931). Similarly, minimum of 10 mm on MBB witnessed in Pseudomonas sp., (MBF9 - AB894829). Toxicity studies proved 50.0% LC50 at 500 μg ml-1 in 24 hrs, whereas Balanus amphitrite resulted in 100% mortality within 12 hrs. Results including weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy, FT-IR and GC-MS confirm 10-Octadecaonic acid as a major corrosion inhibitor from T. ornata and is discovered as a novel antifoulant. Anticorrosion formulation will become available soon.
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