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Structural relaxation and highly viscous flow.

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  • 1Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science (JCNS-1) and Institute for Complex Systems (ICS-1), 52425 Jülich, Germany.

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Summary
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Highly viscous flow in undercooled liquids arises from structural transitions. This explains why relaxation times are longer than predicted by the Maxwell time, revealing key insights into liquid dynamics.

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Area of Science:

  • Condensed matter physics
  • Materials science
  • Rheology

Background:

  • Understanding the behavior of undercooled liquids is crucial for materials science and predicting their flow properties.
  • Viscous flow in these systems is complex and not fully explained by classical models.

Purpose of the Study:

  • To investigate the mechanism behind highly viscous flow in undercooled liquids.
  • To explain the discrepancy between structural relaxation time and Maxwell time.

Main Methods:

  • The study proposes a model based on thermally activated Eshelby transitions.
  • It involves a self-consistent determination of viscosity within this framework.

Main Results:

  • Eshelby transitions create structural changes with differing elastic misfit, driving viscous flow.
  • The model explains the observed structural relaxation time being eight times longer than the Maxwell time.
  • Strongly strained inherent states significantly contribute to fluidity (inverse viscosity).

Conclusions:

  • Thermally activated Eshelby transitions are the primary cause of high viscosity in undercooled liquids.
  • The coexistence of viscous no-return and retardation processes at the Maxwell time is highlighted.