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Updated: Feb 14, 2026

The Effect of Interfacial Chemical Bonding in TiO2-SiO2 Composites on Their Photocatalytic NOx Abatement Performance
Published on: July 4, 2017
Unstrained C-C bond activation and directed fluorination through photocatalytically-generated radical cations
Cody Ross Pitts1, Michelle Sheanne Bloom1, Desta Doro Bume1
1Department of Chemistry , Johns Hopkins University , Baltimore , MD , USA .
Abstract:
Expanding the repertoire of controlled radical fluorination techniques, we present a photosensitized unstrained C-C bond activation/directed monofluorination method using Selectfluor and 9-fluorenone. The reaction is amenable to the opening of multiple 1-acetal-2-aryl substituted rings to yield ω-fluoro carboxylic acids, esters, alcohols, and ketones with relative ease. Initial mechanistic insight suggests radical ion intermediates.
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