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Published on: February 9, 2011
A diarsagermylene and a diarsastannylene stabilised by areneGe/Sn interactions
Keith Izod1, Peter Evans, Paul G Waddell
1Main Group Chemistry laboratories, School of Chemistry, Bedson Building, Newcastle University, Newcastle upon Tyne, NE1 7RU, UK. keith.izod@ncl.ac.uk.
Abstract:
The synthesis and structures of two new diarsatetrylenes {(Dipp)2As}2E are presented [E = Ge, Sn; Dipp = 2,6-diisopropylphenyl]. The high barrier to planarisation of As prevents stabilisation by As-E π-interactions; however, areneGe/Sn interactions stabilise these compounds by up to 181.4 kJ mol-1. This represents a new stabilisation mode for this class of compounds.
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