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K3 B6 O9 F3 : A New Fluorooxoborate with Four Different Anionic Units
Guopeng Han1,2, Guoqiang Shi1,2, Ying Wang1
1CAS Key Laboratory of Functional Materials, and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi, 830011, P. R. China.
Abstract:
K3 B6 O9 F3 , a first fluorooxoborate containing four different units, that is, [BO3 ]3- , [BO4 ]5- , [BO3 F]4- , and [BO2 F2 ]3- , has been designed and synthesized by two different routes. The unique anionic 2∞ [B6 O9 F3 ]3- layers avoid forming terminal oxygen atoms, which are beneficial to enlarge the band gap. The structure-properties relationship of the title compound is discussed.
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